Knowledge What are the white spots on zirconia after sintering? (4 Key Factors)
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Tech Team · Kintek Solution

Updated 2 months ago

What are the white spots on zirconia after sintering? (4 Key Factors)

White spots on zirconia after sintering can be a common issue.

These spots are often caused by the improper application or drying of shading pigments used to color the zirconia.

When shading pigments are not adequately dried before sintering, they can lead to several problems.

One major issue is the reduced lifespan of the sintering furnace's heating elements.

Another problem is pollution within the furnace, which can affect the quality of the zirconia.

1. Shading Process

What are the white spots on zirconia after sintering? (4 Key Factors)

Zirconia used in dental applications is often shaded to match the patient's natural tooth color.

This shading can be applied by the supplier or done in-house by submerging the zirconia in shading liquid or painting it on before sintering.

The effectiveness of the shading and its appearance after sintering can be influenced by the sintering temperature and profile.

2. Effect of Shading Pigments

If the shading pigments are not properly dried before the sintering process, they can cause problems.

The moisture or residue from the pigments can lead to premature failure of the furnace's heating elements, specifically MoSi2 elements, which are sensitive to moisture.

This can result in localized heating irregularities or damage to the elements themselves.

3. Sintering Process

Sintering is a critical step in transforming zirconia from a chalk-like, monoclinic structure to a dense, polytetragonal crystalline state.

This process involves heating zirconia to temperatures between 1,100°C to 1,200°C, which causes it to shrink by about 25% and significantly increases its strength and translucency.

The presence of moisture or poorly applied pigments can disrupt this process, leading to uneven sintering and visible white spots.

4. Importance of Following Manufacturer's Instructions

To avoid such issues, it is crucial to follow the manufacturer's instructions regarding the application and drying of shading pigments.

Proper drying ensures that the pigments are fixed onto the zirconia and do not cause any adverse effects during the high-temperature sintering process.

In summary, the white spots on zirconia after sintering are likely due to the improper handling of shading pigments.

Emphasizing the importance of careful preparation and adherence to sintering protocols can help achieve optimal and aesthetically pleasing results.

Continue exploring, consult our experts

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