The regeneration temperature of activated carbon typically ranges from 200 to 300 °C.
This temperature range is crucial for effectively removing impurities and restoring the adsorptive capacity of the activated carbon.
Below, I will explain the key points related to the regeneration temperature of activated carbon, drawing from the provided references.
Key Points Explained:
Definition and Importance of Regeneration Temperature:
- Regeneration Temperature: The temperature at which activated carbon is heated to remove adsorbed impurities and restore its adsorptive properties.
- Importance: Proper regeneration ensures the longevity and efficiency of activated carbon in various applications, such as water purification and air filtration.
Temperature Range for Regeneration:
- Range: Typically between 200 to 300 °C.
- Reason: At these temperatures, the carbonaceous residue can be burned off without causing significant damage to the carbon structure.
- If oxygen is present, the residue may burn in a highly exothermic reaction, releasing carbon dioxide and/or monoxide.
Exothermic Reactions During Regeneration:
- Exothermic Reaction: The burning of carbonaceous residue is highly exothermic, often with no or little visible flame.
- Temperature Rise: Once carbon combustion starts, the temperature rises spontaneously, turning the residue into a glowing ember.
- Oxidation of Other Elements: At this stage, other elements like nitrogen, sulfur, chlorine, and arsenic may be oxidized and volatilized.
Catalytic Regeneration:
- Catalytic Regeneration Range: Can be conducted between 220–240 °C (Tp) and 320–370 °C (Tc).
- Role of Catalysts: Catalysts reduce the temperature needed for the reaction to occur, making the process more efficient and controllable.
- Effects of Catalysts: Introducing catalysts can affect the reactions inside the chamber, such as carbon atoms dissolving into substrates like Nickel during the cooling phase.
Methods for Regenerating Poisoned Catalysts:
- Box-type Furnace Method: Heating the catalyst to about 850°C to burn off carbon black.
- Air Injection Method: Controlling the temperature in the reaction tank based on the amount of carbon black, typically between 700-800°C or 850°C.
- Termination Criteria: Burning carbon black until the CO content in the discharged gas approaches zero and the CO2 content is less than 1%.
Carbonisation Phases:
- Drying Phase: Above 100°C, water trapped in the pores of the biomass evaporates.
- Thermal Decomposition: Starting between 260 - 300°C, the components of wood break down, releasing volatiles like CO, CO2, CH4, H2, and tars.
In summary, the regeneration temperature of activated carbon is crucial for maintaining its effectiveness and longevity.
The temperature range of 200 to 300 °C ensures that impurities are removed without damaging the carbon structure.
Proper regeneration methods, including the use of catalysts and controlled heating, are essential for optimizing the performance of activated carbon in various industrial applications.
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