Products Lab Consumables & Materials Electrochemical Consumables reference electrode calomel / silver chloride / mercury sulfate
reference electrode calomel / silver chloride / mercury sulfate

Electrochemical Consumables

reference electrode calomel / silver chloride / mercury sulfate

Item Number : ELERA

Price varies based on specs and customizations


$19.90 / set


Applicable temperature range
0 ~ 60℃
Types
Complete and diverse models, customizable
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Introduction

Calomel, Silver Chloride, and Mercury Sulfate are three important compounds used in laboratory equipment and consumables. Calomel, also known as mercurous chloride, is a white or yellowish powder that is insoluble in water. It is used as a reference electrode in electrochemistry and as a cathartic and diuretic in medicine. Silver Chloride is a white or grayish-white powder that is insoluble in water. It is used as a disinfectant, an antiseptic, and a photographic reagent. Mercury Sulfate is a white or yellowish-white powder that is soluble in water. It is used as a disinfectant, an antiseptic, and a fungicide.

We offer complete models of reference electrodes for electrochemical experiments that are resistant to acid and alkali, made with high-quality materials, and designed to be both safe and durable. Additionally, we provide customization options to meet your specific needs.

Technical specifications

Saturated calomel electrode

Single salt bridge
Single salt bridge: 1. Gold plated terminal; 2. Fill port; 3. Mercury wick; 4. Ceramic liquid junction
Double salt bridge
Double salt bridge: 1. U-shaped insert with wire; 2. Filling port; 3. Outer salt bridge; 4. Sand core liquid connection
Elbow
Elbow: 1. U-shaped insert with wire; 2. Filling port; 3. Mercury core; 4. Sand core liquid junction
Features Good reproducibility, accurate potential application
Applicable temperature range 0 ~ 25℃
Dimensions The overall length is 140mm, with the upper tube measuring 9.5mm by 35mm and the lower tube measuring 6mm by 65mm.
Types Amalgam-mercury type. It offers a neutral charge and is available in three variations: single salt bridge, double salt bridge, and bent tube.

Silver chloride electrode 1

Silver Chloride Electrode 1
1. Gold-plated terminal; 2. PTFE rod; 3. Silver wire; 4. Gold-plated terminal
Features suitable for small volumes
Applicable temperature range 0 ~ 40℃
Dimensions 90mm overall length, 4*45mm in the down tube
The electrode properties are Ag/AgCI

Silver chloride electrode 2

1. Gold-plated terminal; 2. Liquid can be added; 3. Silver chloride wire; 4. Sand core liquid connection
Features suitable for any situation
Applicable temperature range 0 ~ 60℃
Dimensions 105mm overall length, 6*45mm in the down tube
The nature of the electrode is Ag/AgCI, and the curved tube can be customized for silver chloride

Saturated silver chloride electrode

Saturated silver chloride electrode
1. Gold-plated binding posts; 2. Filling port; 3. Silver chloride wire; 4. ceramic junction
Features Potential stability
Applicable temperature range 0 ~ 60℃
Dimensions The overall size of the unit is 140mm, with the upper tube measuring φ9.5*35mm and the lower tube measuring φ6*65mm.
Types Ag/AgCI type, neutral electrode; there are two kinds of single salt bridge and double salt bridge

Mercurous sulfate electrode

Mercurous sulfate electrode
1. Gold-plated binding posts; 2. Filling port; 3. Silver chloride wire; 4. ceramic junction
Features use acidic electrolyte
Applicable temperature range 0 ~ 60℃
Dimensions The overall size of the unit is 140mm, with the upper tube measuring φ9.5*35mm and the lower tube measuring φ6*65mm.
Types Mercury type, acid electrode; there are two kinds of single salt bridge and double salt bridge

Mercury Oxide Electrode

Single salt bridge
Single salt bridge: 1. Gold-plated terminal; 2. Fill port; 3. Mercury wick; 4. Ceramic junction
Double salt bridge
Double salt bridge: 1. U-shaped insert with wire; 2. Filling port; 3. Outer salt bridge; 4. Sand core liquid connection
Features Suitable for alkaline electrolytes
Applicable temperature range 0 ~ 60℃
Dimensions The overall size of the unit is 140mm, with the upper tube measuring φ9.5*35mm and the lower tube measuring φ6*65mm.
Types Mercury type, alkaline electrode; there are two kinds of single salt bridge and double salt bridge

Silver Chloride Type 218

Silver Chloride Type 218
1. U-shaped plug connection; 2. Filling port; 3. Silver chloride wire; 4. Ceramic sand core
Features Suitable for long-term reactions
Applicable temperature range 0 ~ 60℃
Dimensions The overall size of the unit is 145mm, the lower tube measuring φ9.2*120mm. Wiring is U-shaped blade
Types The nature of the electrode is Ag/AgCI type, which can react unattended for a long time

Silver Chloride Type 219

Silver Chloride Type 219
1. U-shaped plug connection; 2. Filling port; 3. Silver chloride wire; 4. Ceramic sand core
Features Suitable for long-term reactions
Applicable temperature range 0 ~ 60℃
Dimensions The overall size of the unit is 145mm, the lower tube measuring φ9.2*120mm. Wiring is U-shaped blade
Types The nature of the electrode is Ag/AgCI type, and the second liquid junction of the double junction type can be added on demand

Sand core salt bridge

Sand core salt bridge
1. Sand core; 2. Platinum sheet

 

Features Protective electrode, easy to use
Applicable temperature range 0 ~ 80℃
Dimensions Standard φ10*70mm, extended φ10*100mm
Types The built-in sand core liquid junction is used to protect the electrode and reduce the liquid junction potential

Lukin Capillary

Lukin Capillary
1. Glass junction; 2. Glass junction
Features Protective electrode, easy to use
Applicable temperature range 0 ~ 80℃
Dimensions Standard φ10*70mm, extended φ10*100mm
Used to protect the electrode and reduce the liquid junction potential

Variable diameter sand core salt bridge

Variable diameter sand core salt bridge
1. Sand core liquid contact; 2. Sand core liquid contact
Features Protective electrode, easy to use
Applicable temperature range 0 ~ 80℃
Dimensions φ12*70mm / φ6*70mm / φ6*100
Used to protect the electrode and reduce the liquid junction potential

Straight Sand Core Salt Bridge

Straight Sand Core Salt Bridge
1. Filling port; 2. Sand core liquid connection; 3. 4. Sand core liquid junction; 5. Outer Salt Bridge;
Features Protective electrode, easy to use
Applicable temperature range 0 ~ 50℃
Dimensions φ6*80mm / φ10*80mm
The guard electrode reduces the liquid junction potential

Detail & Parts

reference electrodesreference electrode detailreference electrode detail 2reference electrode and electrolytic cellreference electrode and electrolytic cell 2reference electrode and electrolytic cell 3reference electrode and electrolytic cell 4

Principle

The Calomel / Silver Chloride / Mercury Sulfate principle is based on the electrochemical reaction between calomel (Hg2Cl2) and silver chloride (AgCl) in the presence of mercury sulfate (HgSO4). When the calomel electrode is immersed in a solution containing chloride ions, the following reaction occurs:

Hg2Cl2(s) + 2e- → 2Hg(l) + 2Cl-(aq)

This reaction generates an electrical potential that is proportional to the concentration of chloride ions in the solution. The silver chloride electrode serves as a reference electrode with a stable and well-defined potential, providing a stable reference point for measuring the potential of the calomel electrode.

Applications

Calomel / Silver Chloride / Mercury Sulfate electrodes are widely used in electrochemistry, particularly in applications such as:

  • Reference electrodes in electrochemical cells and potentiometric measurements
  • Determination of redox potentials and electrochemical reactions
  • Corrosion studies and electrochemical impedance spectroscopy
  • Electroplating and electrorefining processes
  • Monitoring and control of chemical processes in various industries

Designed for You

KinTek provide deep custom made service and equipment to worldwide customers, our specialized teamwork and rich experienced engineers are capable to undertake the custom tailoring hardware and software equipment requirements, and help our customer to build up the exclusive and personalized equipment and solution!

Would you please drop your ideas to us, our engineers are ready for you now!

FAQ

What are the advantages of using a calomel electrode?

Calomel electrodes are easy to set up, reproducible, convenient, easy to transport, compact, and require little space. They also do not require a separate salt bridge and have a potential that does not change appreciably with time or temperature.

What are the different types of reference electrodes available?

Common reference systems include:* Saturated Calomel (Hg/HgCl)* Ag/AgCl (wire or cartridge)* Cu/CuSO4* Hg/HgSO4* Hg/HgO

When should I use a calomel electrode instead of an Ag/AgCl electrode?

Use a calomel electrode if your sample is incompatible with Ag or Cl. Calomel electrodes are also more stable but contain mercury, making them unsuitable for certain applications (e.g., food, beverage, environmental studies).

What is reference electrode with an example?

A reference electrode is an electrode with a stable and known electrode potential, used in electrochemical measurements and devices. An example of a reference electrode is the Standard Hydrogen Electrode (SHE), which has a potential of 0.000 V and an activity of H+ of 1 Molar. Other examples of reference electrodes include the Normal Hydrogen Electrode (NHE), Saturated Calomel Electrode (SCE), Silver Chloride Electrode, Copper-Copper Sulfate Electrode, and the pH Electrode. Reference electrodes are used in building electrochemical cells and determining the potential of the other half-cell.

What is the role of reference electrode?

The role of the reference electrode is to complete the electrical circuit necessary for an electrochemical measurement by providing the second electrode of a complete electrode cell whose total potential is measured. The reference electrode achieves this by providing contact with the sample through its liquid junction. For a reference electrode to be useful, it must provide both a stable and reproducible potential to which the indicating electrode potential can be compared. Most difficulties experienced while performing measurements with electrodes can be traced to the reference electrode, and more specifically, to the reference electrode's liquid junction.

What is reference electrode used for?

A reference electrode is used to provide a stable and defined potential for electrochemical measurements. It consists of an internal element, typically silver-silver chloride, surrounded by an electrolyte-containing filling solution. The purpose of the reference electrode is to complete the electrical circuit necessary for an electrochemical measurement by providing the second electrode of a complete electrode cell whose total potential is measured. Most electrodes combine a stable reference and a working cell in one probe, but separate reference electrodes are available for certain applications. The choice of reference electrode depends on factors such as sample compatibility, stability, and temperature considerations.

What is a reference electrode vs counter electrode?

A reference electrode is used as a comparison point for the potential of the working electrode in an electrochemical experiment. It must maintain a stable potential throughout the experiment. Common examples include Ag/AgCl, Ag/Ag+ and the saturated calomel electrode (SCE). On the other hand, a counter electrode transfers electrons between itself and some species in solution, in order to prevent inhibition of electron transfer at the working electrode. It must transfer electrons quickly and is commonly made of platinum metal, such as a platinum wire or a high surface area platinum gauze electrode.

What is the difference between standard and reference electrode?

Standard electrode potential is the potential difference between a half-cell and a standard reference electrode. A reference electrode, on the other hand, is an electrode that has a stable and well-known electrode potential. The key difference is that the standard electrode potential is a relative value, while the reference electrode potential is an absolute value. The standard electrode potential can be used to predict the direction of electron flow in a reaction, whereas the reference electrode potential is used to measure the potential of other half-cells and determine the absolute potential of a given electrode.
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4.7

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The reference electrode is performing as promised and has met my expectations.

Zainab Bromen Van Beurden

4.8

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The reference electrode arrived quickly and in perfect condition. I am very satisfied with the purchase.

Fidan Bal

4.9

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The quality of the reference electrode is excellent. It is well-made and durable.

Damir Engels

4.6

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I have been using the reference electrode for a few weeks now and I am very happy with it. It is easy to use and gives accurate results.

Zsofia Kónya

4.7

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The reference electrode is a great value for the price. It is affordable and works just as well as more expensive models.

Aramıs Karaca

4.8

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I would definitely recommend the reference electrode to other researchers. It is a reliable and affordable option.

Józef Włodarczyk

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The reference electrode has been a great addition to my lab. It has helped me to improve the accuracy of my experiments.

Ali Can Mustafa

4.7

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I am very satisfied with the reference electrode. It is a high-quality product that has met all of my needs.

Ceylan Karabaş

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The reference electrode is a valuable tool for my research. It has helped me to obtain more accurate data.

Aishah Bennett

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