An auxiliary electrode is an electrode used in a three-electrode electrochemical cell for voltammetric analysis. It provides a pathway for current flow in the electrochemical cell without passing a significant current through the reference electrode. The most commonly used material for the auxiliary electrode is platinum, due to its inertness. It can be isolated from the working electrode using a glass frit to prevent byproducts generated from contaminating the main test solution. The work of the auxiliary electrode is to pass all the current so that the current at the working electrode can be controlled.
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auxiliary electrode
Electrochemical workstation/potentiostat
Item Number : KT-CHIP
Platinum Sheet Platinum Electrode
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We have the best Auxiliary Electrode solutions for your electrochemical cell needs. Our extensive range of materials includes electrochemically inert materials such as graphite, gold, carbon, and platinum. The auxiliary electrode is responsible for passing all the current so that the current at the working electrode can be controlled. Our auxiliary electrodes are fabricated from high-quality materials to ensure the accuracy and precision of your electrochemical measurements. We also offer bespoke designs for more unique applications to meet almost any customer requirements.
Applications of Auxiliary Electrode
- Used in a three-electrode electrochemical cell for voltammetric analysis
- Provides a pathway for current flow in the electrochemical cell without passing a significant current through the reference electrode
- Provides a means of applying input potential to the working electrode
- Used to make a connection to the electrolyte for the purpose of applying a current to the working electrode
- Functions as a cathode whenever the working electrode is operating as an anode and vice versa
- Passes all the current so that the current at the working electrode can be controlled
- May be isolated from the working electrode using a glass frit to prevent byproducts generated at the auxiliary electrode from contaminating the main test solution
- Often fabricated from electrochemically inert materials such as gold, platinum, or carbon
- Material used to make an auxiliary electrode must be an inert material like graphite or a noble metal such as gold, carbon, or platinum
- Used to balance the removed or added charge by the working electrode
- Swings to extreme potentials at the solvent window edges where the oxidation or reduction of the solvent occurs
- Divides the role of supplying electrons as well as referencing the potential between two different electrodes
- Does not pass any current in reference electrode
Advantages of Auxiliary Electrode
- Enables controlled current flow in electrochemical cells
- Provides a pathway for current flow without passing a significant current through the reference electrode
- Allows for applying input potential to the working electrode
- Isolates the working electrode from byproducts generated at the auxiliary electrode
- Prevents contamination of the main test solution
- Functions as a cathode whenever the working electrode is operating as an anode and vice versa
- Made from electrochemically inert materials such as gold, platinum, or carbon
- In sealed cell design, it protects the cell against destructive pressure rise during charging
- Allows the potential of the working electrode to be measured against a known reference electrode without compromising the stability of that reference electrode by passing current over it
Our Auxiliary Electrode is a cost-effective solution for your electrochemical testing needs. We offer a wide range of materials, including graphite, gold, platinum, and carbon, to suit your specific requirements. Our custom design service allows you to tailor the electrode shape and size to fit your testing set-up, ensuring accurate and reproducible results.
FAQ
What is the function of auxiliary electrode?
The auxiliary electrode, also known as the counter electrode, is an electrode used in a three-electrode electrochemical cell for voltammetric analysis or other reactions where an electric current is expected to flow. Its primary function is to provide a pathway for current flow in the electrochemical cell without passing a significant current through the reference electrode. It provides a means of applying input potential to the working electrode. The auxiliary electrode may be isolated from the working electrode to prevent any byproducts generated from contaminating the main test solution. It is often fabricated from electrochemically inert materials such as gold, platinum, or carbon.
What is the difference between auxiliary and reference electrode?
The main difference between auxiliary and reference electrode lies in their function in an electrochemical cell. The auxiliary electrode, also known as the counter electrode, is used to facilitate charge transfer to and from the analyte and pass all the current so that the current at the working electrode can be controlled. On the other hand, the reference electrode is used to reference when measuring and controlling the potential of the working electrode and does not pass any current. The reference electrode has a fixed potential, while the potential of the auxiliary electrode can change.
What materials are commonly used for auxiliary electrodes?
The choice of materials for auxiliary electrodes depends on the specific electrochemical system and the desired reaction. Common materials for auxiliary electrodes include platinum, graphite, stainless steel, and certain metal alloys. These materials are typically inert and do not participate in the desired electrochemical reaction, ensuring that the auxiliary electrode's role remains solely as a conductor for current flow.
How do auxiliary electrodes affect the performance of an electrochemical cell?
Auxiliary electrodes play a crucial role in the performance of electrochemical cells. They help maintain a balanced electrical potential, minimizing side reactions or unwanted reactions at the working electrode. The choice of appropriate materials for the auxiliary electrode is essential to prevent contamination or interference with the desired electrochemical process. Additionally, the design and positioning of the auxiliary electrode within the cell can impact overall efficiency and uniformity of current distribution. Proper selection and placement of auxiliary electrodes can enhance the performance, accuracy, and reproducibility of electrochemical measurements or processes.
Why are auxiliary electrodes necessary in electrochemical systems?
Auxiliary electrodes are necessary in electrochemical systems to maintain electrical neutrality and ensure the flow of current. In many electrochemical reactions, the desired reaction occurs at the working electrode, while the auxiliary electrode acts as a counterbalance. It helps to complete the circuit by providing a path for the flow of electrons or ions, thereby allowing the continuous movement of charge and ensuring the overall electrochemical reaction proceeds smoothly and efficiently.
Are there any limitations or considerations when using auxiliary electrodes?
When using auxiliary electrodes, several limitations and considerations should be taken into account. The choice of materials for the auxiliary electrode is critical to prevent any unwanted reactions or contamination that could affect the desired electrochemical process. Compatibility between the auxiliary electrode and the electrolyte or reactants should be considered to ensure stability and long-term performance. Additionally, the design and positioning of the auxiliary electrode should be carefully optimized to minimize current distribution issues or potential interference with the working electrode. It is also essential to regularly monitor and maintain the auxiliary electrode to prevent degradation or contamination that could impact its performance. Finally, the size and shape of the auxiliary electrode should be considered to ensure compatibility with the specific electrochemical cell or system being used.
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