Knowledge What is the process of making silicon carbide? (7 Key Methods Explained)
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Tech Team · Kintek Solution

Updated 2 months ago

What is the process of making silicon carbide? (7 Key Methods Explained)

Silicon carbide (SiC) is a synthetically produced compound known for its hardness, wear resistance, and thermal properties.

It is valuable in various industries due to its unique characteristics.

The process of making silicon carbide involves several industrial methods, including sintering, reaction bonding, crystal growth, and chemical vapor deposition (CVD).

1. Sintering

What is the process of making silicon carbide? (7 Key Methods Explained)

Sintered SiC is produced from pure SiC powder with non-oxide sintering aids.

The process involves using conventional ceramic forming techniques and sintering the material in an inert atmosphere at temperatures up to 2000°C or higher.

This method results in a dense and strong material suitable for high-temperature applications.

2. Reaction Bonding

Reaction bonded SiC is made by infiltrating compacts of mixtures of SiC and carbon with liquid silicon.

The silicon reacts with the carbon, forming additional silicon carbide, which bonds the SiC particles together.

This method is particularly useful for creating complex shapes and structures.

3. Crystal Growth

Manufacturers use chemical vapor deposition to grow monocrystalline SiC films on silicon wafer substrates.

This process involves various techniques that can introduce n-type and p-type dopants into the SiC films, enhancing their electrical properties.

This method is crucial for producing high-quality SiC crystals used in electronics manufacturing.

4. Chemical Vapor Deposition (CVD)

CVD is used to produce SiC with very low electrical resistance, making it a reasonable conductor of electricity.

This property allows for the fabrication of fine features using EDM (Electrical Discharge Machining) methods, which are useful for generating tiny holes with high aspect ratios.

The CVD material is also known for its low density, high stiffness, extreme hardness, and wear resistance.

5. Preparation Methods

Industrial methods for preparing SiC powder include the Acheson method (carbothermal reduction of quartz with carbon materials), silicon dioxide low-temperature carbothermal reduction, and silicon-carbon direct reaction.

These methods vary in temperature requirements and the type of SiC crystal (α or β) produced.

6. Crystal Forms

SiC exists in two main crystal forms, α and β.

β-SiC has a cubic crystal structure and is stable at temperatures below 1600°C.

Above this temperature, β-SiC slowly transforms into various α-SiC polytypes, which are more stable at higher temperatures.

7. Industrial Applications

The production of silicon carbide involves a range of sophisticated techniques tailored to create materials with specific properties suitable for various industrial applications, including semiconductors, ceramics, and high-temperature equipment.

Continue exploring, consult our experts

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