Plasma deposition is a sophisticated process used to create thin films on various substrates.
How does plasma deposition work? 7 Key Steps Explained
1. Creation of Plasma
The plasma is generated by an electrical discharge, typically between 100 – 300 eV, between electrodes.
This discharge creates a glowing sheath around the substrate, providing thermal energy that drives chemical reactions.
2. Chemical Reactions in Plasma
Precursor gas molecules in the plasma collide with highly energized electrons.
These reactions occur initially in the plasma and then, via gas flow, the reactive species travel to the substrate.
3. Deposition on Substrate
Upon reaching the substrate, the reactive species react and are absorbed on the surface, growing into films.
The chemical by-products are desorbed and pumped away.
4. Control Parameters
The deposition rate and film properties such as thickness, hardness, or refractive index can be controlled by adjusting gas flow rates and operating temperatures.
5. Types of Plasma Deposition
One common method is Plasma-Enhanced Chemical Vapor Deposition (PECVD), which operates at low pressures (<0.1 Torr) and relatively low substrate temperatures (room temperature to 350°C).
PECVD uses plasma to provide energy for the deposition reactions, reducing the need for high substrate temperatures and minimizing stress on the film interface, thus enhancing bonding strength.
6. Advantages of PECVD
Compared to conventional Chemical Vapor Deposition (CVD), PECVD offers lower deposition temperatures, good consistency and step coverage on uneven surfaces, tighter control of the thin film process, and high deposition rates.
7. Mechanism of Deposition
In the plasma, the negative electrical potential from the cathode attracts positively charged target atoms.
The energetic collisions within the plasma cause ions to accelerate into the target with sufficient kinetic energy to dislodge molecules, which then cross the vacuum chamber to coat the substrate.
This process is highly versatile, capable of depositing various materials over objects of different sizes and shapes, making it a valuable technique in advanced manufacturing.
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