Wood undergoes significant changes during pyrolysis, a process of thermal decomposition that occurs without oxygen or with limited oxygen supply.
5 Key Transformations Explained
1. Initial Heating and Outgassing
As wood is heated, it begins to smoke and release combustible gases.
The wood surface cracks and chars, turning black.
This charring cools the wood as the gases boil off, similar to how water maintains a constant temperature while boiling.
2. Char Formation and Heating
Once the outgassing nearly ceases, the temperature of the char increases, reaching a red heat.
Carbon molecules vaporize from the char and react with oxygen to produce a faint blue-violet flame.
3. Final Oxidation and Ash Production
After all carbon has been vaporized and oxidized, only a small amount of whitish ash remains.
4. Pyrolysis Definition and Mechanism
Pyrolysis is the thermal decomposition of materials at elevated temperatures, often in an inert atmosphere.
The process involves the breaking of long chain molecules into smaller molecules due to excessive thermal vibration.
This decomposition leads to the formation of volatile products and a char residue, which is rich in carbon.
5. Chemical Pathways in Wood Pyrolysis
Wood, primarily composed of cellulose, hemicellulose, and lignin, undergoes different chemical reactions during pyrolysis.
Cellulose breaks down into levoglucosan and aliphatic hydrocarbon chains, along with carbon dioxide, carbon monoxide, and water.
Lignin decomposes to produce phenolic compounds, and hemicellulose yields furfurals.
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