Plasma enhanced chemical vapor deposition (PECVD) is a technique used in the formation of thin films.
It uses plasma to enhance the chemical reactivity of the reacting substances.
This method allows for the deposition of solid films at lower temperatures compared to conventional chemical vapor deposition methods.
5 Key Points Explained
1. Activation of Reaction Gas
In PECVD, the gas near the surface of the substrate is ionized.
This activates the reaction gas.
The ionization is facilitated by the generation of low-temperature plasma.
This enhances the chemical activity of the reacting substances.
The activation of the gas is crucial as it allows for the deposition of films at lower temperatures.
This is not possible with conventional chemical vapor deposition methods.
2. Improvement of Surface Activity
The ionization process also leads to cathode sputtering on the surface of the substrate.
This sputtering improves the surface activity.
It allows not only common thermochemical reactions but also complex plasma chemical reactions to occur on the surface.
The combined action of these chemical reactions results in the formation of the deposited film.
3. Methods of Stimulating Glow Discharge
The glow discharge, which is essential for the ionization process, can be stimulated through various methods.
These include radio frequency excitation, DC high voltage excitation, pulse excitation, and microwave excitation.
Each method has its own advantages and is chosen based on the specific requirements of the deposition process.
4. Properties of Plasma in PECVD
The plasma used in PECVD is characterized by high kinetic energy of electrons.
This is crucial for activating chemical reactions in the gas phase.
The plasma is a mixture of ions, electrons, neutral atoms, and molecules.
It is electrically neutral on a macro scale.
The plasma in PECVD is typically a cold plasma, formed by low-pressure gas discharge.
This is a non-equilibrium gas plasma.
This type of plasma has unique properties, such as the random thermal motion of electrons and ions exceeding their directional motion.
The average thermal motion energy of electrons is significantly higher than that of heavy particles.
5. Advantages of PECVD
PECVD offers several advantages over other CVD techniques.
These include better quality and stability of the deposited films.
It also typically has faster growth rates.
The method is versatile and can utilize a broad range of materials as precursors.
This includes those that are typically considered inert.
This versatility makes PECVD a popular choice for various applications.
These include the manufacturing of diamond films.
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