Heat treatment processes rely on various gases to control the atmosphere and achieve the desired metallurgical properties without unwanted reactions.
5 Essential Gases You Should Know
1. Inert Gases
Inert gases like argon, helium, and nitrogen are widely used in heat treatment, especially for non-ferrous metals such as copper, brass, and aluminum.
These gases create a non-reactive environment, preventing oxidation and other unwanted chemical reactions.
Argon and helium are considered more inert than nitrogen, which can react with some steels at high temperatures.
These gases are often used in combinations like Ar/He, Ar/He/N2, and N2/He to optimize their protective properties.
2. Reducing Agents
Hydrogen is used as a reducing agent in heat treatment processes, particularly for purifying iron and copper oxides.
It helps in removing oxygen from the metal surfaces, preventing oxidation.
Hydrogen is not inert and must be handled carefully due to its flammability and potential for causing hydrogen embrittlement in some metals.
3. Hydrocarbons
Hydrocarbon gases like methane (CH4), propane (C3H8), ethane (C2H6), and acetylene (C2H2) are used to produce carbon-rich atmospheres within the furnace.
These gases decompose at high temperatures, releasing nascent carbon which can interact with the metal surface, affecting its carbon content and properties.
The choice of hydrocarbon gas is crucial to avoid sooting and other undesirable effects.
4. Ammonia
Ammonia is utilized for its nitrogen and hydrogen content.
It can be used as a source of nitrogen in nitriding processes or as a source of hydrogen in reducing atmospheres.
The use of ammonia allows for precise control over the nitrogen and hydrogen content in the furnace atmosphere, which is critical for certain heat treatment processes.
5. Endothermic Atmospheres
On an industrial scale, protective atmospheres often consist of mixtures of carbon monoxide (CO), hydrogen (H2), nitrogen (N2), carbon dioxide (CO2), and trace amounts of water vapor.
These gases are produced using endothermic generators or by injecting nitrogen and methanol mixtures directly into the furnace.
The stability of these atmospheres, particularly the CO content, is crucial for accurate carbon control during austenitizing.
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