Metals that cannot be hardened by heat treatment include pure aluminum (Series 1xxx) and some aluminum alloys that do not undergo a martensite transformation or precipitation hardening. These include aluminum-manganese alloys (Series 3xxx) and low magnesium aluminum-magnesium alloys (Series 5xxx).
Explanation:
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Pure Aluminum (Series 1xxx): Pure aluminum does not undergo significant hardening through heat treatment because it lacks the alloying elements necessary for precipitation hardening or martensite formation. It primarily strengthens through cold working and annealing, which are not considered heat treatment processes that harden the metal.
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Aluminum-Manganese Alloys (Series 3xxx): These alloys, such as 3003, 3004, 3105, and 3005, do not harden significantly through heat treatment. The primary strengthening mechanism in these alloys is through work hardening and annealing. The manganese in these alloys contributes to improved corrosion resistance and moderate strength, but they do not form the necessary precipitates or undergo martensitic transformations that would harden them through heat treatment.
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Low Magnesium Aluminum-Magnesium Alloys (Series 5xxx): For alloys like 5005, 5050, and 5052, which contain a low level of magnesium, the primary strengthening mechanism is also work hardening and annealing. While magnesium can contribute to some hardening in higher concentrations, these lower magnesium alloys do not exhibit significant hardening through heat treatment processes like precipitation hardening or martensitic transformation.
These metals and alloys primarily rely on other methods of strengthening, such as cold working and annealing, which alter the microstructure and properties without the need for heat treatment processes that induce hardening through precipitation or phase transformations.
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