Quartz undergoes several phase transformations as temperature increases. At atmospheric pressure, the low-temperature form is α-quartz, which transforms into β-quartz at around 573 ℃. This transformation is spontaneous and reversible. When the temperature rises further to above 873 ℃, β-quartz transforms into the tridymite phase. Understanding these transformations is crucial for applications involving high-temperature environments, especially when using materials like quartz windows that need to withstand such conditions.
Key Points Explained:
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α-Quartz at Low Temperatures:
- At atmospheric pressure, quartz exists in its α-quartz form at low temperatures. This is the most stable form of quartz under standard conditions and is commonly found in nature.
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Transformation to β-Quartz at 573 ℃:
- As the temperature increases to around 573 ℃, α-quartz undergoes a phase transformation to β-quartz. This transformation is spontaneous and reversible, meaning that if the temperature decreases, β-quartz will revert back to α-quartz.
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Further Transformation to Tridymite at 873 ℃:
- When the temperature exceeds 873 ℃, β-quartz transforms into the tridymite phase. Tridymite is a high-temperature polymorph of silica and is less dense than quartz. This phase is stable at high temperatures and is often found in volcanic rocks.
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Implications for High-Temperature Applications:
- Understanding these phase transformations is essential for applications that involve high temperatures, such as in the use of quartz windows. These windows must be able to withstand high temperatures without undergoing detrimental phase changes that could affect their structural integrity and optical properties.
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Relevance to Material Selection:
- For equipment and consumables purchasers, knowing the high-temperature behavior of quartz is crucial when selecting materials for high-temperature environments. Ensuring that the material can maintain its properties under operational conditions is key to the longevity and reliability of the equipment.
By understanding these phase transformations, one can make informed decisions about the use of quartz in high-temperature applications, ensuring that the material properties align with the operational requirements.
Summary Table:
Phase | Temperature Range | Characteristics |
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α-Quartz | Below 573 ℃ | Stable at low temperatures, commonly found in nature. |
β-Quartz | 573 ℃ to 873 ℃ | Forms from α-quartz at 573 ℃, reversible transformation. |
Tridymite | Above 873 ℃ | High-temperature polymorph, stable at high temperatures, found in volcanic rocks. |
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